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AEO7
1. PRODUCT AND COMPANY IDENTIFICATION
Product name : NEODOL 25-7
Product code : V2453, V2668
Synonyms : Alcohols, C12-15, ethoxylated
CAS-No: 68131-39-5
Manufacturer or supplier's details
Supplier:SHELL EASTERN CHEMICALS (S)
A REGISTERED BUSINESS OF SHELL EASTERN
TRADING (PTE) LTD (UEN:198902087C)
9 North Buona Vista Drive , #07-01
The Metropolis Tower 1
Singapore 138588
Singapore
Telephone : +65 6384 8737
Telefax: +65 6384 8454
Recommended use of the chemical and restrictions on use
Recommended use:Use in detergent manufacture.
Restrictions on use: This product must not be used in applications other than the above without first seeking the advice of the supplier.
Other information: NEODOL is a trademark owned by Shell Trademark Management B.V. and Shell Brands Inc. and used by affiliates of Royal Dutch Shell plc.
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance | Hazy to semi-solid liquid. |
Colour | Data not available |
Odour | mild |
Health Hazards |
Harmful if swallowed.
May be harmful in contact with skin.
Causes serious eye damage.
|
Safety Hazards | Not classified as flammable but will burn. |
Environmental Hazards |
Toxic to aquatic life.Harmful to aquatic life with long lasting effects.
|
GHS Classification
Acute toxicity (Oral) : Category 4
Acute toxicity (Dermal) : Category 5
Serious eye damage: Category 1
Acute aquatic toxicity : Category 2
Chronic aquatic toxicity: Category 3
GHS label elements
Hazard pictograms:
Signal word : Danger
Hazard statements: PHYSICAL HAZARDS:
Not classified as a physical hazard under GHS criteria. HEALTH HAZARDS:
H302 Harmful if swallowed.
H313 May be harmful in contact with skin.
H318 Causes serious eye damage.
ENVIRONMENTAL HAZARDS:
H401 Toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements:Prevention:
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P273 Avoid release to the environment.
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P330 Rinse mouth.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
Storage:
No precautionary phrases.
Disposal:
P501 Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.
Other hazards which do not result in classification
Repeated exposure may cause skin dryness or cracking.
Physical and chemical hazards
|
Not classified as flammable but will burn. |
Health Hazards |
Inhalation: No specific hazards under normal use conditions.
Skin: May be harmful in contact with skin.
Causes mild skin irritation.
Repeated exposure may cause skin dryness or cracking.
Eyes: Causes serious eye damage.
Ingestion: Harmful if swallowed.
|
Environmental Hazards |
Toxic to aquatic life.Harmful to aquatic life with long lasting effects.
|
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Substance
Chemical nature : A mixture of primary alcohol ethoxylates.
Hazardous components
Chemical name | CAS-No. | Classification | Concentration [%] |
C12-15 Alcohol |
68131-39-5 |
Acute Tox.4; H302 |
100 |
For explanation of abbreviations see section 16.
4. FIRST-AID MEASURES
General advice : DO NOT DELAY. Keep victim calm. Obtain medical treatment immediately.
If inhaled : No treatment necessary under normal conditions of use. If symptoms persist, obtain medical advice.
In case of skin contact : Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If needed, transport to the nearest medical facility for additional treatment.
In case of eye contact : Immediately flush eye(s) with plenty of water.Remove contact lenses, if present and easy to do. Continue rinsing. Transport to the nearest medical facility for additional treatment.
If swallowed : Do not induce vomiting.If victim is alert, rinse mouth and drink 1/2 to 1 glass of water to help dilute the material. Do not give liquids to a drowsy, convulsing, or unconscious person.Transport to nearest medical facility for additional treatment. If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Rinse mouth.
Protection of first-aiders : When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, injury and surroundings.
Notes to physician : Treat symptomatically.Consult a Poison Control Centre for guidance.
5. FIRE-FIGHTING MEASURES
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Handling
Storage
Conditions for safe storage : Refer to section 15 for any additional specific legislation covering the packaging and storage of this product.
Other data : Tanks should be fitted with heating coils in areas where the ambient temperatures are below the recommended product handling temperatures. Heating coil skin temperatures should not exceed 100 °C. Bulk storage tanks should be diked (bunded). Vapours from tanks should not be released to atmosphere.Breathing losses during storage should be controlled by a suitable vapour treatment system. Nitrogen blanket recommended for large tanks (capacity 100 m3 or higher). Insulation (lagging) will minimize heat loss in areas of low ambient temperature. Tanks should be fitted with heating coils in areas where ambient conditions can result in handling temperatures below the freezing point/pour point of the product.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Components with workplace control parameters
Biological occupational exposure limits
No biological limit allocated.
Monitoring Methods
Engineering measures
Personal protective equipment
Protective measures
Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers.
Respiratory protection : If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. If air-filtering respirators are suitable for conditions of use: Select a filter suitable for the combination of organic gases and vapours [Type A/Type P boiling point >65°C (149°F)].
Eye protection : Wear goggles for use against liquids and gas.Wear full face shield if splashes are likely to occur.
Skin and body protection: Skin protection is not required under normal conditions of use. For prolonged or repeated exposures use impervious clothing over parts of the body subject to exposure. If repeated and/or prolonged skin exposure to the substance is likely, then wear suitable gloves tested to relevant Standard,and provide employee skin care programmes.
Thermal hazards : Not applicable
Hygiene measures: Wash hands before eating, drinking, smoking and using the toilet. Launder contaminated clothing before re-use. Do not ingest. If swallowed then seek immediate medical assistance. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or subsequent recycle.
Environmental exposure controls
General advice : Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. Information on accidental release measures are to be found in section 6.
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
Reactivity : Stable at normal ambient temperature and pressure., May oxidise in the presence of air.